The N-acylated derivatives of parent complex [{(μ-SCH2) 2NH}Fe2(CO)6] as active site models of fe-only hydrogenases: Synthesis, characterization, and related properties

DOI: 10.1002/ejic.200700845

Source and publish data:

European Journal of Inorganic Chemistry p. 291 - 297 (2008)

Update date:2022-07-31

Topics:

Authors:

Song, Li-Cheng

Wang, Liang-Xing

Yin, Bang-Shao

Li, Yu-Long

Zhang, Xiao-Guang

Zhang, Yuan-Wei

Luo, Xiang

Hu, Qing-Mei

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Article abstract of DOI:10.1002/ejic.200700845

A series of N-acylated diiron azadithiolate complexes as H-cluster models was synthesized and structurally characterized. Treatment of parent complex [{(μ-SCH₂)₂NH}Fe₂(CO)₆] (A) with 2-chloroacetic acid in the p

Full text of DOI:10.1002/ejic.200700845

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