UEBER POLYGERMANE XVI. SYNTHESE α,ω-DICHLORIERTER POLYGERMANE Cl(Ph2Ge)nCl (n = 2,3,4) DURCH GERMYLEN-EINSCHUB

DOI: 10.1016/0022-328X(86)80294-7

Source and publish data:

Journal of Organometallic Chemistry p. 155 - 166 (1986)

Update date:2022-07-29

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Authors:

Haeberle, Karl

Draeger, Martin

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Article abstract of DOI:10.1016/0022-328X(86)80294-7

The germylene Ph2Ge<*> of Ph2GeHCl and NEt3 inserts in excess Ph2GeHCl and forms polygermanes Cl(Ph2Ge)nH.This one-pot reaction and subsequent chlorination to Cl(Ph2Ge)nCl has been optimized.Increasing amounts of NEt3 step up the yields of higher polygerm

Full text of DOI:10.1016/0022-328X(86)80294-7

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