1,3-SYN DIASTEREOSELECTIVE REDUCTION OF β-HYDROXYKETONES UTILIZING ALKOXYDIALKYLBORANES

DOI: 10.1016/S0040-4039(00)95673-9

Source and publish data:

Tetrahedron Letters p. 155 - 158 (1987)

Update date:2022-08-05

Topics:

Authors:

Chen, Kau-Ming

Hardtmann, Goetz E.

Prasad, Kapa

Repic, Oljan

Shapiro, Michael J.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)95673-9

Sodium borohydride reduction of β-hydroxyketones in presence of alkoxydialkylboranes 1-7 as complexing agents, produced 1,3-syn diols in at least 98:2 ratio.As illustrated with examples 8-17 this method is quite general and superior to those described in

Full text of DOI:10.1016/S0040-4039(00)95673-9

Products guided by the article

Product name:(E)-(3R,5R)-7-[3-(4-Fluoro-phenyl)-1-isopropyl-1H-indol-2-yl]-3,5-dihydroxy-hept-6-enoic acid methyl ester

Cas No:110454-40-5

R&D Labs maybe for 110454-40-5

JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Shanghai TBBMed Co.,Ltd

website:http://www.tbbmed.com

Contact:86--21-50498136

Address:Room 6002, Building 7-1, No.160 Basheng Road,Pudong Area,Shanghai China
Antaeus Bio-technology Co., LTD(expird)

Contact:021-31252569

Address:shanghai pudong
Du-Hope International Group

website:http://www.np-chem.com

Contact:0086-25-52346877

Address:199, Jian Ye Road, Nanjing, China
BOC Sciences

website:https://www.bocsci.com/

Contact:1-631-485-4226

Address:Ramsey Road

Relevant to this article

Trimethylgermylation of ketones

Doi:10.1021/om00155a019
(1987)
Palladium-Catalyzed Hydroxycarbonylation of Aryl and Vinyl Halides or Triflates by Acetic Anhydride and Formate Anions ?

Doi:10.1021/ol0354371
(2003)
Doi:10.1007/BF01427004
()
UTILIZATION OF A NITRENIUM ION CYCLIZATION IN A SYNTHESIS OF A PHOTOACTIVE PROSTAGLANDIN, 17-(4-AZIDO-2-HYDROXYPHENYL)-18,19,20-TRINORPROSTAGLANDIN F_2α

Doi:10.1016/S0040-4039(00)95644-2
(1987)
New efficient asymmetric synthesis of taranabant, a CB1R inverse agonist for the treatment of obesity

Doi:10.1021/op800270e
(2009)
STEREO- AND REGIOSPECIFIC SYNTHESES TO PROVIDE CONJUGATED (E, Z)- AND (Z,Z)-ALKANIDES, AND ARYLATED (Z)-ALKENES IN EXCELLENT YIELDS VIA THE PALLADIUM-CATALYZED CROSS COUPLING REACTIONS OF (Z)-1-ALKENYLBORONATES WITH 1-BROMOALKENES AND ARYL IODIDES

Doi:10.1016/S0040-4039(00)83869-1
(1986)

Article Doi