Tetrahedron Letters p. 155 - 158 (1987)
Update date:2022-08-05
Topics:
Chen, Kau-Ming
Hardtmann, Goetz E.
Prasad, Kapa
Repic, Oljan
Shapiro, Michael J.
Sodium borohydride reduction of β-hydroxyketones in presence of alkoxydialkylboranes 1-7 as complexing agents, produced 1,3-syn diols in at least 98:2 ratio.As illustrated with examples 8-17 this method is quite general and superior to those described in
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Doi:10.1021/om00155a019
(1987)Doi:10.1021/ol0354371
(2003)Doi:10.1007/BF01427004
()Doi:10.1016/S0040-4039(00)95644-2
(1987)Doi:10.1021/op800270e
(2009)Doi:10.1016/S0040-4039(00)83869-1
(1986)
