1,3-SYN DIASTEREOSELECTIVE REDUCTION OF β-HYDROXYKETONES UTILIZING ALKOXYDIALKYLBORANES

DOI: 10.1016/S0040-4039(00)95673-9

Source and publish data:

Tetrahedron Letters p. 155 - 158 (1987)

Update date:2022-08-05

Topics:

Authors:

Chen, Kau-Ming

Hardtmann, Goetz E.

Prasad, Kapa

Repic, Oljan

Shapiro, Michael J.

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Article abstract of DOI:10.1016/S0040-4039(00)95673-9

Sodium borohydride reduction of β-hydroxyketones in presence of alkoxydialkylboranes 1-7 as complexing agents, produced 1,3-syn diols in at least 98:2 ratio.As illustrated with examples 8-17 this method is quite general and superior to those described in

Full text of DOI:10.1016/S0040-4039(00)95673-9

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