Stereospecific Anti Radical Elimination Reaction from β-Nitro Sulfones

DOI: 10.1021/jo00232a010

Source and publish data:

Journal of Organic Chemistry p. 5111 - 5116 (1987)

Update date:2022-07-30

Topics:

Authors:

Ono, Noboru

Kamimura, Akio

Kaji, Aritsune

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Article abstract of DOI:10.1021/jo00232a010

β-Nitro sulfones react with tin radicals to give alkenes, where the nitro and sulfonyl groups are cleaved in an anti stereospecific way.The specificity is lost when the elimination reaction is induced by sodium sulfide.The high stereospecificity of the re

Full text of DOI:10.1021/jo00232a010

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