Stereospecific Anti Radical Elimination Reaction from β-Nitro Sulfones

DOI: 10.1021/jo00232a010

Source and publish data:

Journal of Organic Chemistry p. 5111 - 5116 (1987)

Update date:2022-07-30

Topics:

Authors:

Ono, Noboru

Kamimura, Akio

Kaji, Aritsune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00232a010

β-Nitro sulfones react with tin radicals to give alkenes, where the nitro and sulfonyl groups are cleaved in an anti stereospecific way.The specificity is lost when the elimination reaction is induced by sodium sulfide.The high stereospecificity of the re

Full text of DOI:10.1021/jo00232a010

Products guided by the article

Product name:(2S,3R)-2,4-Dimethyl-2-nitro-3-phenylsulfanyl-pentan-1-ol

Cas No:110511-67-6

R&D Labs maybe for 110511-67-6

Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Jiangsu Hualun Chemical Industry Co., Ltd

website:http://www.hualunchem.com

Contact:+86-0514-86464168 86507985

Address:39# Middle Renmin Road, Dinghuo Town
Chemvon Biotechnology Co. Ltd.

website:http://www.chemvon.com

Contact:86-21-58550039;86-21-31268550-8004

Address:Suite B-10#, 6999 Chuansha Road, Pudong District, Shanghai 201202, China
Xi'an Tizan Tech & Industry Co., Ltd.

Contact:86-18629066522

Address:C3009 TANG FENG INTERNATIONAL PLAZA, NO.18 FENGHUI NAN ROAD, XI'AN HIGH TECH ZONE, 710075 CHINA.

Relevant to this article

From branched self-assemblies to branched mesoporous silica nanoribbons

Doi:10.1039/b812016a
(2008)
Convenient synthesis and antimicrobial activity of new 3-substituted 5-(benzofuran-2-yl)-pyrazole derivatives

Doi:10.1002/ardp.200800119
(2008)
NOYAINE, THE FIRST C-RING SECOCULARINE ALKALOID

Doi:10.1016/S0040-4039(00)85260-0
(1986)
Aminoacid-derived mercaptoimidazoles

Doi:10.1039/b810678a
(2009)
SYNTHESIS OF THE FRAGMENT GlcNAc-α(1-P-6)-GlNAc OF THE CELL WALL POLYMER OF STAPHYLOCOCCUS LACTIS HAVING REPEATING N-ACETYL-D-GLUCOSAMINE PHOSPHATE UNITS

Doi:10.1016/S0040-4039(00)85450-7
(1986)
Synthesis of dl-standishinal and its related compounds for the studies on structure-activity relationship of inhibitory activity against aromatase

Doi:10.1016/j.bmc.2007.01.031
(2007)

Article Doi