Journal of Organic Chemistry p. 5247 - 5254 (1987)
Update date:2022-08-04
Topics:
Buriks, Rudy S.
Lovett, Eva G.
Tetriary (2-hydroxyethyl)dialkylamines reacted with epichlorohydrin to form mixtures containing equal amounts of 2-(hydroxymethyl)-4,4-dialkylmorpholinium chlorides and perhydro-6-hydroxy-4,4-dialkyl-1,4-oxazepinium chlorides.Secondary (2-hydroxyethyl)alkylamines gave a 9:1 ratio of the corresponding bases in agreement with the prediction of Baldwin's rules.
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(1987)
