PALLADIUM-CATALYSED REDUCTIVE ADDITION OF ARYL IODIDES TO ARYL AND ALKYLETHYNYLSILANES: A STEREO AND REGIOSELECTIVE ROUTE TO FUNCTIONALIZED 2,2-DISUBSTITUTED VINYLSILANES

DOI: 10.1016/S0040-4039(00)87818-1

Source and publish data:

Tetrahedron Letters p. 6397 - 6400 (1986)

Update date:2022-08-04

Topics: Palladium Stereoselective Functionalized Aryl Iodides Regioselective Catalysed Reductive addition

Authors:

Arcadi, A.

Cacchi, S.

Marinelli, F.

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Article abstract of DOI:10.1016/S0040-4039(00)87818-1

Aryl and alkylethynylsilanes are converted into 2,2-disubstituted vinylsilanes containing various common functional groups in the presence of aryl iodides, a palladium catalyst, formic acid, and a tertiary or secondary amine with high stereoselectivity an

Full text of DOI:10.1016/S0040-4039(00)87818-1

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