Journal of the Chemical Society. Chemical communications p. 334 - 335 (1987)
Update date:2022-08-04
Topics:
Yamamoto, Koji
Ando, Hiroyuki
Chikamatsu, Hiroaki
An efficient microbial resolution of 1,3-diphenylpropane-1,3-diol (4) has been achieved by exposing the corresponding diacetate to Trichoderma viride; a redcutive cleavage of chiral acetals (6) derived from (4) with hydride reagent (Br2AlH), Cl2AlH) affords optically active alcohols (8) if hugh enantiomeric purities.
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