Tetrahedron Letters p. 5109 - 5112 (1990)
Update date:2022-08-04
Topics:
La Villa, Joseph A.
Goodman, Joshua L.
Photoacoustic calorimetry and product studios on the photochemical decomposition of methylhalodiazirines indicate two pathways for the formation of vinyl halides: 1) a [1,2] intramolecular hydrogen shift of the initially formed methylhalocarbene, 2) an excited state pathway which circumvents the ground state carbene. Results suggest that carbene/olefin or carbene/alcohol complexes are not involved in vinyl halide formation.
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