Synthetic Communications p. 85 - 92 (2009)
Update date:2022-09-26
Topics:
Drapo, Jeanette R.
Priefer, Ronny
In an attempt to regenerate Ti(0) from TiOx for possible application in a catalytic McMurry coupling reaction, a praseodymium-based pinacol reaction was uncovered. This reaction formed the two products 2,3-diphenyl-2,3-butanediol (3) and α,β-dimethyl-α-phenyl-β-[(trimethylsilyl)oxy]- benzene-ethanol (6) in a 1:3 ratio. Copyright Taylor & Francis Group, LLC.
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