Tetrahedron Letters p. 3715 - 3718 (1984)
Update date:2022-07-29
Topics: Lewis acid Enantiomerically pure Chiral 13C NMR Isolation Reagent Organoaluminum Compounds Starting Material Reaction Conditions Reaction Mechanism
Suzuki, Keisuke
Katayama, Eiji
Matsumoto, Takashi
Tsuchihashi, Gen-ichi
Reductive pinacol type rearrangement of chiral α-mesyloxy ketones was effected by organoaluminiums (DIBAL in combination with Et3Al or Et2AlCl) leading to enantiomerically pure 2-aryl- or 2-alkenyl-1-propanols.
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