Synthesis of Enantiomerically Pure (4S)-2-Alken-4-olides via (2S)-1-Phenylsulfonyl-2-alkanols

DOI: 10.1055/s-1987-27956

Source and publish data:

Synthesis p. 389 - 390 (1987)

Update date:2022-08-04

Topics:

Authors:

Tanikaga, Rikuhei

Hosoya, Ken

Kaji, Aritsune

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1055/s-1987-27956

Reduction of 1-chloro-3-phenylsulfonyl-2-propanone with baker's yeast, followed by epoxidation and alkylation with Grignard reagents, yields enantiomerically pure (2S)-2-phenylsulfonyl-2-alkanols, which are converted into (4S)-2-alken-4-olides in 100perce

Full text of DOI:10.1055/s-1987-27956

Products guided by the article

Product name:(2S)-1-phenylsulphonyl-3-phenylpropan-2-ol

Cas No:111613-17-3

R&D Labs maybe for 111613-17-3

wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157
Shanghai Standard Biotech Co., Ltd.

Contact:+86-18502101150

Address:Room 103, Building 2nd, NO.720, Cailun Road , Pudong District, Shanghai, China
ZUNYI CITY BEI YUAN CHEMICAL CO., LTD

website:http://www.china-beiyuan.com

Contact:+86-851-27751258

Address:Shawan Town, Huichuan District, Zunyi City, Guizhou Province, China
GIHI CHEMICALS CO.,LIMITED

Contact:+86-571-86217390

Address:No.567 Dengcai Street,Sandun,Westlake District,Hangzhou310030,Zhejiang,China.
ENERGYCO LTD.

Contact:+86-25-83719363

Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China

Relevant to this article

Doi:10.1021/jo01077a021
(1960)
Development of robust heterogeneous chiral rhodium catalysts utilizing acid?base and electrostatic interactions for efficient continuous-flow asymmetric hydrogenations

Doi:10.1021/jacs.0c08109
(2020)
Access to the 2,3-dihydropyridazin-3-one and as-triazino[3,4-a]phthalazine ring systems from 4-aryl-2-oxo-butanoic acids [1]

Doi:10.1002/jhet.5570240114
(1987)
A CONVENIENT SYNTHESIS OF 2-DEOXY-2-<(R)-3-HYDROXYTETRADECANAMIDO>-3-O-<(R)-3-HYDROXYTETRADECANOYL>-α-D-GLUCOPYRANOSE 1-PHOSPHATE (LIPID X)

Doi:10.1016/0008-6215(87)80202-1
(1987)
Doi:10.1039/jr9500001505
(1950)
Additions to bicyclic olefins. II. A convenient synthesis of apobornene and apocamphor.

Doi:10.1021/jo00830a023
(1970)

Article Doi