Synthesis of Enantiomerically Pure (4S)-2-Alken-4-olides via (2S)-1-Phenylsulfonyl-2-alkanols

DOI: 10.1055/s-1987-27956

Source and publish data:

Synthesis p. 389 - 390 (1987)

Update date:2022-08-04

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Authors:

Tanikaga, Rikuhei

Hosoya, Ken

Kaji, Aritsune

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Article abstract of DOI:10.1055/s-1987-27956

Reduction of 1-chloro-3-phenylsulfonyl-2-propanone with baker's yeast, followed by epoxidation and alkylation with Grignard reagents, yields enantiomerically pure (2S)-2-phenylsulfonyl-2-alkanols, which are converted into (4S)-2-alken-4-olides in 100perce

Full text of DOI:10.1055/s-1987-27956

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