Synthesis p. 542 - 547 (1987)
Update date:2022-07-30
Topics: Regioselectivity Column chromatography Yield Catalyst Nucleophile Stereochemistry Rearrangement Diels-Alder Reaction Solvent Effects Substituent Effects Cycloaddition Ring Expansion Spectroscopic Characterization Kinetic Control Thermodynamic Control Electrophilic addition π-conjugation Resonance stabilization
Eicher, Theophil
Abel, Manfred
Triafulvenes 1 are reacted with a series of donor substituted 1,3-dienes 2 in a Diels-Alder addition to yield bicyclic methylene cyclopropanes 3.The primary Diels-Alder adducts are transformed either to 1,6-diphenyl-substituted heptafulvenes 5 or to other
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(2011)
