Journal of the American Chemical Society p. 501 - 509 (1988)
Update date:2022-08-04
Topics: Isomeric Rearrangements Experimental Molecular formula Atoms Phenyl ring
Chapman, Orville L.
Johnson, Jeffery W.
Mahon, Robert J. Mc
West, Paul R.
We present evidence for a mechanism in which the isomeric tolylmethylenes interconvert via methylcycloheptatetraene intermediates.Photolysis (>470 nm) of diazo compounds 1-4, matrix isolated in argon at 10 K, generates triplet tolylmethylenes 8-11.Photoly
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