
Tetrahedron Letters p. 211 - 214 (1987)
Update date:2022-08-05
Topics:
Yoshida, Jun-ichi
Murata, Toshiki
Isoe, Sachihiko
Electrochemical oxidation of 1-trimethylsilyl-1,3-dienes in methanol afforded 1,1,4-trimethoxy-2-butene derivatives, which were readily hydrolyzed to the corresponding α,β-unsaturated aldehydes.By combination of this electrochemical reaction with the synthesis of 1-trimethylsilyl-1,3-dienes from carbonyl compounds, 1,3-bis(trimethylsilyl)propene provides a β-formylvinyl anion equivalent.
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