Advanced Synthesis and Catalysis p. 2045 - 2049 (2015)
Update date:2022-07-30
Topics:
Feng, Xiaoming
Kang, Tengfei
Wang, Zhen
Lin, Lili
Liao, Yuting
Zhou, Yuhang
Liu, Xiaohua
An N,N′-dioxide/zinc bis(trifluoromethylsulfonyl)imide complex has been developed as an efficient catalyst for the highly enantioselective Diels-Alder reaction of cyclopentadiene with alkynones. Various 2-acyl substituted norbornadiene derivatives were obtained in moderate to high yields (up to 99%) with good enantiomeric excesses (up to 95%).
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