Construction of an Optically Active 7-Oxabicyclonon-4-en-3-one. Skeleton from D-Glucose, and Its Transformation to Some Pseudo-Hexopyranoses

DOI: 10.1246/bcsj.60.1727

Source and publish data:

Bulletin of the Chemical Society of Japan p. 1727 - 1740 (1987)

Update date:2022-08-04

Topics:

Authors:

Tadano, Kin-ichi

Ueno, Yoshihide

Fukabori, Chiyoko

Hotta, Yukinori

Suami, Tetsuo

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Article abstract of DOI:10.1246/bcsj.60.1727

A versatile chiral compound, (1R,6R,8R,9R)-8,9-isopropylidenedioxy-7-oxabicyclo<4.3.0>non-4-en-3-one (6), was efficiently synthesized from D-glucose.The synthesis featured an intramolecular aldol cyclization of 3-C-acetylmethyl-3-deoxy-1,2-O-isopropyliden

Full text of DOI:10.1246/bcsj.60.1727

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