THE REACTION OF CARBOHYDRATE-DERIVED ALKOXYALDEHYDES WITH METHOXYCARBONYLMETHYLENETRIPHENYLPHOSPHORANE: STEREOSELECTIVE SYNTHESIS OF β-UNSATURATED ESTERS

DOI: 10.1016/S0040-4020(01)81502-7

Source and publish data:

Tetrahedron p. 1895 - 1902 (1987)

Update date:2022-07-29

Topics:

Authors:

Valverde, Serafin

Martin-Lomas, Manuel

Herradon, Bernardo

Garcia-Ochoa, Silvestre

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Article abstract of DOI:10.1016/S0040-4020(01)81502-7

The reaction of several carbohydrate-derived alkoxyaldehydes with methoxycarbonylmethylenetriphenylphosphorane affords α,β-unsaturated esters with Z-stereoselectivity.The stereoselectivity depends on the substrate structure and the nature of the solvent u

Full text of DOI:10.1016/S0040-4020(01)81502-7

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