
Tetrahedron p. 1895 - 1902 (1987)
Update date:2022-07-29
Topics:
Valverde, Serafin
Martin-Lomas, Manuel
Herradon, Bernardo
Garcia-Ochoa, Silvestre
The reaction of several carbohydrate-derived alkoxyaldehydes with methoxycarbonylmethylenetriphenylphosphorane affords α,β-unsaturated esters with Z-stereoselectivity.The stereoselectivity depends on the substrate structure and the nature of the solvent u
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