Tetrahedron Letters p. 1561 - 1564 (1987)
Update date:2022-08-03
Topics:
Bateson, John H.
Quinn, Alison M.
Southgate, Robert
Allylic oxidation of 4-allyl-1-dimethyl-t-butylsilylazetidin-2-ones (5,7) gave the 4-(1-hydroxyprop-2-ene-1-yl) derivatives (6,8).Radical benzoyloxylation of the silylated 8-oxo-7-azabicyclo<4.2.0>oct-3-ene (18) provided four allylic monobenzoates.Progression of (8) and (29) afforded, respectively, 4-acyloxy olivanic acid analogues containing trans- (16) and cis- (31) substituents at C-6.
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Doi:10.1021/acs.orglett.8b00093
(2018)Doi:10.1002/chem.200901843
(2009)Doi:10.1002/ardp.198700027
(1987)Doi:10.1002/ardp.19873200813
(1987)Doi:10.1021/jo00246a008
(1988)Doi:10.1016/S0020-1693(00)84385-6
(1987)
