Chemistry of Aminoketene Dithioacetals: Preparation of Protected α-Amino Aldehydes and Ketones and Formation of Nitrogen Heterocycles

DOI: 10.1039/c39870000775

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Journal of the Chemical Society. Chemical communications p. 775 - 776 (1987)

Update date:2022-09-26

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Authors:

Page, Philip C. Bulman

Niel, Monique B. van

Westwood, Donald

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Article abstract of DOI:10.1039/c39870000775

The ambient anion (2) derived from primary aminoketene dithioacetal (1, R = Ph) reacts with alkyl halides at the carbon atom to give remarkably stable imines which may be reduced to give protected α-amino ketones using borane in quantitative yield, and un

Full text of DOI:10.1039/c39870000775

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