Chemistry of Aminoketene Dithioacetals: Preparation of Protected α-Amino Aldehydes and Ketones and Formation of Nitrogen Heterocycles

DOI: 10.1039/c39870000775

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 775 - 776 (1987)

Update date:2022-09-26

Topics:

Authors:

Page, Philip C. Bulman

Niel, Monique B. van

Westwood, Donald

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870000775

The ambient anion (2) derived from primary aminoketene dithioacetal (1, R = Ph) reacts with alkyl halides at the carbon atom to give remarkably stable imines which may be reduced to give protected α-amino ketones using borane in quantitative yield, and un

Full text of DOI:10.1039/c39870000775

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:α-(2-methyl-1,3-dithian-2-yl)benzylamine

Cas No:112701-11-8

R&D Labs maybe for 112701-11-8

Dalian Join King Biochemical Tech. Co., Ltd.

Contact:0411 39216206

Address:814 First State Blvd
FOSHAN NANHAI ZHONGNAN PHARMACEUTICAL FACTORY

Contact:0086-0757-85609331

Address:XIAHENGTIAN INDUSTRIAL ZONE,SHAYONG VILLAGE,LISHUI TOWN
Nanjing Chemipioneer Pharma&Tech Co.,Ltd

website:http://www.chemipioneer.com.cn

Contact:+86-25-52685700

Address:Room 305，A Block，Biological-Medicine Building，Business Start-up Center，Xin-ke 1st Road, High-tech development zone，Nanjing city，Jiangsu Province, China
Shaanxi Sinuote Biotech Co.,Ltd

Contact:+86-29-68859685

Address:No 18,Taiyuan Road ,Xi'an city ,China
EGBERT CORPORATION

Contact:+86 18616952870

Address:Area

Relevant to this article

Helical primary structures of 1,3-spiroannelated five-membered rings: (±)-trispiro[4.1.1.4.2.2]heptadecane and (±)-tetraspiro[4.1.1.1.4.2.2.2]heneicosane

Doi:10.1016/j.tet.2008.12.025
(2009)
Umpolung of o-Hydroxyaryl Azomethine Ylides: Entry to Functionalized ?-Aminobutyric Acid under Phosphine Catalysis

Doi:10.1021/acs.orglett.8b02297
(2018)
Synthesis of a unique trisaccharide having an acetal linkage between open-chain and cyclic sugar found in the cell wall of Proteus

Doi:10.1016/j.tetasy.2008.12.006
(2008)
Catalytic Hydrolysis of Phosphate Esters in Microemulsions. 3. Analysis of the Hydrolysis Products of p-Nitrophenyl Diphenyl Phosphate via 31P NMR

Doi:10.1021/jo00244a030
(1988)
A New Convenient Synthetic Method for 3,4-Diaryl-2,6-piperidinediones

Doi:10.1007/BF00815326
(1987)
Synthesis and structure-activity relationships of ferrocenyl tamoxifen derivatives with modifed side chains

Doi:10.1002/chem.200801108
(2009)

Article Doi