COPPER(II) IN ORGANIC SYNTHESIS. VI REACTION OF THE COPPER(II) ACETATE COMPLEX OF 1-METHYLISATIN-3-CHLOROPHENYLHYDRAZONE WITH DIMETHYL ACETYLENEDICARBOXYLATE.

DOI: 10.1016/S0040-4020(01)86889-7

Source and publish data:

Tetrahedron p. 2843 - 2852 (1987)

Update date:2022-07-29

Topics:

Authors:

Coda, Corsico A.

Desimoni, G.

Invernizzi, Gamba A.

Quadrelli, P.

Righetti, P. P.

Tacconi, G.

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Article abstract of DOI:10.1016/S0040-4020(01)86889-7

The copper(II) complex of 1-methylisatin -3-p-chlorophenylhydrazone (2) reacted with dimethyl acetylenedicarboxylate (DMAD) in accordance to two reaction pathways.Oxidation performed by Cu(2+) gave 1-metyl-3-carbenindolin-2-one (12), trapped by DMAD to gi

Full text of DOI:10.1016/S0040-4020(01)86889-7

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