Synthesis, Complexation, and X-Ray Structure of a New Type of Binucleating Macrocycle Incorporating Both Soft and Hard Ligating Sites

DOI: 10.1039/C39870000974

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 974 - 977 (1987)

Update date:2022-08-03

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Authors:

Staveren, Catherina J.

Reinhoudt, David N.

Eerden, Johan

Harkema, Sybolt

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Article abstract of DOI:10.1039/C39870000974

A macrocyclic ligand with both a Schiff base moiety and a polyether cavity forms mono- and bi-nuclear complexes; X-ray analysis of the mononuclear Ba(ClO4)2 complex shows that Ba²⁺ is co-ordinated in the polyether cavity.

Full text of DOI:10.1039/C39870000974

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