Protecting group and solvent control of stereo-and chemoselectivity in glucal 3-carbamate amidoglycosylation

DOI: 10.1021/ol900126q

Source and publish data:

Organic Letters p. 1527 - 1530 (2009)

Update date:2022-08-04

Topics:

Authors:

Gupta, Ritu

Sogi, Kimberly M.

Bernard, Sarah E.

Decatur, John D.

Rojas, Christian M.

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Article abstract of DOI:10.1021/ol900126q

In the Rh₂(OAc)₄-catalyzed amidoglycosylation of glucal 3-carbamates, anomeric stereoselectivity and the extent of competing C3-H oxidation depend on the 4O and 6O protecting groups. Acyclic protection permits high α-anomer selectivi

Full text of DOI:10.1021/ol900126q

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