Methods for Indole Alkaloid Synthesis: A Study of the Compatibility of the Indole-2,3-Quinodimethane Strategy for the Synthesis of 16-Methoxy-Substituted Aspidosperma-Type Alkaloids. Synthesis of (+)- and (-)-16-Methoxytabersonine

DOI: 10.1021/ja00215a039

Source and publish data:

Journal of the American Chemical Society p. 2242 - 2248 (1988)

Update date:2022-07-29

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Authors:

Cardwell, Kevin

Hewitt, Brian

Ladlow, Mark

Magnus, Philip

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Article abstract of DOI:10.1021/ja00215a039

4-Methoxy-2-nitroaniline (5) is converted into 1-carbomethoxy-6-methoxy-3-formyl-2-methylindole (10) in an overall yield of 28percent through five steps.The derived imine from 10 and 2-(phenylthio)ethylamine on treatment with acid chloride (+/-)-12 gave h

Full text of DOI:10.1021/ja00215a039

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