Methods for Indole Alkaloid Synthesis: A Study of the Compatibility of the Indole-2,3-Quinodimethane Strategy for the Synthesis of 16-Methoxy-Substituted Aspidosperma-Type Alkaloids. Synthesis of (+)- and (-)-16-Methoxytabersonine

DOI: 10.1021/ja00215a039

Source and publish data:

Journal of the American Chemical Society p. 2242 - 2248 (1988)

Update date:2022-07-29

Topics:

Authors:

Cardwell, Kevin

Hewitt, Brian

Ladlow, Mark

Magnus, Philip

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00215a039

4-Methoxy-2-nitroaniline (5) is converted into 1-carbomethoxy-6-methoxy-3-formyl-2-methylindole (10) in an overall yield of 28percent through five steps.The derived imine from 10 and 2-(phenylthio)ethylamine on treatment with acid chloride (+/-)-12 gave h

Full text of DOI:10.1021/ja00215a039

Products guided by the article

Product name:(1S,2R,3S,4R)-3-Propionyl-bicyclo[2.2.1]hept-5-ene-2-carboxylic acid; compound with (1R,2S)-2-methylamino-1-phenyl-propan-1-ol

Cas No:113471-34-4

R&D Labs maybe for 113471-34-4

Shanghai Send Pharmaceutical Technology Co., Ltd.

website:http://www.shsendpharma.com

Contact:021-58088081, +8613585868794

Address::Room A601, Building 1,NO. 800 Qingdai Road Pudong District Shanghai,China
MS( MAOSHENG )Chemical CO.,LTD

Contact:+86-519-82726678.82726378

Address:TAOXI INDUSTRY ZONE JINTAN
Changsha Goomoo Chemical Technology Co.Ltd

Contact:+86-731-82197655

Address:No.649,Chezhan Rd.(N),Changsha,Hunan,China
Shanghai chemrole co.,ltd

Contact:021-50278900

Address:No.6,Room 201 ,Lane 299,bisheng road ,shanghai ,china
JiangXi Keyuan Biopharma Co., LTD.

Contact:+86-563-6833666

Address:Guangde Fine Chemical Zone, Anhui Province, China

Relevant to this article

Peracid Oxidation of 4-Isoxazolines as a Method for the Preparation of α, β-Unsaturated Carbonyl Compounds

Doi:10.1021/jo00245a021
(1988)
An efficient synthesis of [¹³C₆]-3,5-dichloroaniline

Doi:10.1002/jlcr.1521
(2008)
Total synthesis of dl-cephalotaxine. The first example of an intramolecular 4 + 2 cycloaddition where the dienophile has been delivered from the face opposite to the tethering moiety

Doi:10.1021/ja00215a076
(1988)
THE CHEMISTRY OF PHOTOLYTICALLY AND THERMALLY GENERATED α-KETOCARBENES FROM IODONIUM YLIDES OF β-DIKETONES

Doi:10.1016/S0040-4039(00)96535-3
(1987)
Nickel-Catalyzed Cross-Coupling of Redox-Active Esters with Boronic Acids

Doi:10.1002/anie.201605463
(2016)
NEW SYNTHESIS OF BENZO<α>QUINOLIZIDIN-2-ONES via PROTECTED 2-ARYL-4-PIPERIDONES

Doi:10.1016/S0040-4020(01)86842-3
(1987)

Article Doi