Tetrahedron Letters p. 7989 - 7992 (1994)
Update date:2022-08-04
Topics:
Samizu, Kiyohiro
Ogasawara, Kunio
Birch reduction of several 5-aryl-4,5-dihydro-1,3-dioxepins gave rise to 3-arylbutanal in moderate to good yields by hydrogenolytic cleavage of the homobenzylic-homoallylic carbon-oxygen bond when the benzylic-allylic carbon is tertiary.However, the reaction did not take place when the benzylic-allylic carbon is quaternary.Moreover, the reaction was found to proceed with complete racemization at the benylic-allylic center indicating a concurrent elimination-reduction pathway to be involved.
View MoreShijiazhuang Sdyano Fine Chemical Co., Ltd
Contact:+86-311-89830448
Address:NO.48 Ta Nan Road,Yuhua District,Shijiazhuang,Hebei,China
SPRING CHEMICAL INDUSTRY CO.,LTD
Contact:86-187-66672125
Address:linchi industry park.zouping
SICHUAN ZHONGBANG NEW MATERIAL CO., LTD
website:http://www.zhongbangst.com
Contact:86-830-2585019
Address:sichuan,china
Contact:+86-0512-88957371
Address:shanghai
Changzhou BaoKang Pharmaceutical & Chemical Co., Ltd
Contact:(86) 519-88782201 88784080 88785278
Address:Henglin town, changzhou,Jiangsu
Doi:10.1016/j.tetasy.2008.12.023
(2008)Doi:10.1016/j.carres.2008.11.002
(2009)Doi:10.1021/jo00246a021
(1988)Doi:10.1021/jo00245a044
(1988)Doi:10.1016/j.tetlet.2009.01.005
(2009)Doi:10.1016/S0960-894X(03)00411-6
(2003)
