Influence of Electrostatic Forces upon the Efficiency of Charge Separation for the Zinc Porphyrin/Methyl Viologen System

DOI: 10.1039/f19827801873

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Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1873 - 1886 (1982)

Update date:2022-07-29

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Authors:

Richoux, Marie-Claude

Harriman, Anthony

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Article abstract of DOI:10.1039/f19827801873

The bimolecular rate constant for quenching the triplet excited state of a metalloporphyrin by methyl viologen depends upon the elctronic charge on the porphyrin ring.The rate constant increases with increased electrostatic attraction between the reactant

Full text of DOI:10.1039/f19827801873

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