INTRAMOLECULAR FORMAL IRON-CATALYZED ENE REACTIONS: THE STEREOSELECTIVE AND REGIOCONTROLLED FORMATION OF SUBSTITUTED TETRAHYDROPYRANS

DOI: 10.1016/S0040-4039(00)96797-2

Source and publish data:

Tetrahedron Letters p. 5627 - 5630 (1987)

Update date:2022-07-29

Topics:

Authors:

Takacs, James M.

Anderson, Lawrence G.

Creswell, Mark W.

Takacs, Beckie E.

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Article abstract of DOI:10.1016/S0040-4039(00)96797-2

The iron-catalyzed six-membered ring carbocyclizations of 5-oxa-2,8,10-undecatriene derivatives proceed with high regio- and stereoselectivity to yield trans-3,4-disubstituted tetrahydropyrans.Substrates containing an alkyl substituent at the 4- or the 7-

Full text of DOI:10.1016/S0040-4039(00)96797-2

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