Tetrahedron Letters p. 2061 - 2064 (1987)
Update date:2022-07-29
Topics:
Sarkar, Tarun K.
Ghosh, Sunil K.
A new and efficient route to terminally-substituted (E)-allylsilanes is described based on the preference for Krief-Reich elimination in several β-seleno-γ-silyl alcohols, readily available by diastereoselective addition of various Grignard reagents or aldol reaction on 2-(phenylseleno)-3-(trimethylsilyl)propanal(9).
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