Journal of Organometallic Chemistry p. 141 - 150 (1987)
Update date:2022-07-30
Topics:
Mitchell, T. N.
Reimann, W.
The influence of intramolecular coordination and solvent effects on the formation and stability of α-stannylvinyllithium reagents RR'C=C(Li)SnMe3 (R'=H, alkyl aryl) has been investigated; intramolecular coordination via a 5-membered ring is particularly effective.Mechanisms for the isomerisation and thermal decomposition of RR'C=C(Li)SnMe3 are discussed, and multinuclear NMR data (119Sn, 13C and 1H) for these species are presented.
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