Substitution nucleophile aromatique SNAr sur le dimethyl-2,6-chlorobenzenetricarbonylchrome

DOI: 10.1016/0022-328X(89)88045-3

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Journal of Organometallic Chemistry p. 123 - 130 (1989)

Update date:2022-08-02

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Authors:

Rose-Munch, Francoise

Rose, Eric

Semra, Assia

Filoche, Michele

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Article abstract of DOI:10.1016/0022-328X(89)88045-3

2-Lithio-2-methylpropionitrile and 2-lithio-2-phenyl-1,3-dithiane react with 2,6-dimethylchlorobenzenetricarbonylchromium (1) to give after treatment with CF3CO2H, a single arenetricarbonylchromium complex via tele-para nucleophilic aromatic substitutions.Complex 1 has a staggered conformation in the solid state and in solution.

Full text of DOI:10.1016/0022-328X(89)88045-3

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