Journal of the American Chemical Society p. 2501 - 2505 (1988)
Update date:2022-08-04
Topics:
Zhai, Dongguan
Zhai, Weixu
Williams, Robert M.
Reaction of halo acetals containing O, N, or S heteroatoms with tri-n-butyltin acetylides in the presence of ZnCl2 in CCl4 leads to the formation of α-alkynyl ethers, amines, and sulfides in good yields.The methodology is exemplified with the synthesis of amino acids and C-glycosides.
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