The Mechanism of the Quinamine Rearrangements

DOI: 10.1021/ja00218a039

Source and publish data:

Journal of the American Chemical Society p. 3247 - 3252 (1988)

Update date:2022-09-26

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Authors:

Boduszek, Bogdan

Shine, Henry J.

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Article abstract of DOI:10.1021/ja00218a039

Acid-catalyzed rearrangement of 6-bromo-2,4-dimethyl-4(phenylamino)cyclohexa-1,4-dienone (1, a quinamine) in aqueous methanol gives, from a so-called quinamine rearrangement, 4'-amino-6-bromo-2,4-dimethyldiphenyl ether (2) and a number of byproducts.The r

Full text of DOI:10.1021/ja00218a039

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