Anchimeric Assistance by and Migration of the Vinyl Group in Reactions of Sterically Hindered Organosilicon Compounds of the Type (Me3Si)2C(SiMe2CH=CH2)(SiR2X)

DOI: 10.1039/P29870001047

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1047 - 1058 (1987)

Update date:2022-07-29

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Authors:

Ayoko, G. Adefikayo

Eaborn, Colin

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Article abstract of DOI:10.1039/P29870001047

The compound VsiSiMe2I (1) is very similar in reactivity to (Me3Si)3CSiMe2I (2) in reaction with methanol and with alkali-metal salts in MeOH or MeCN, but (1) is much the more reactive towards electrophiles which induce rate-d

Full text of DOI:10.1039/P29870001047

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