Anchimeric Assistance by and Migration of the Vinyl Group in Reactions of Sterically Hindered Organosilicon Compounds of the Type (Me3Si)2C(SiMe2CH=CH2)(SiR2X)

DOI: 10.1039/P29870001047

Source and publish data:

Journal of the Chemical Society. Perkin transactions II p. 1047 - 1058 (1987)

Update date:2022-07-29

Topics:

Authors:

Ayoko, G. Adefikayo

Eaborn, Colin

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/P29870001047

The compound VsiSiMe2I (1) is very similar in reactivity to (Me3Si)3CSiMe2I (2) in reaction with methanol and with alkali-metal salts in MeOH or MeCN, but (1) is much the more reactive towards electrophiles which induce rate-d

Full text of DOI:10.1039/P29870001047

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Silane, [(ethenyldimethylsilyl)(methylphenylsilyl)methylene]bis[trimethyl-

Cas No:114048-46-3

R&D Labs maybe for 114048-46-3

Luna Chemicals Co.,Ltd.

Contact:+86-570-4336358

Address:No.87 Building,Tianqian,Sidu Town
Zhejiang Newfine Industry Co.,Ltd.

Contact:+86-573-82262042

Address:No.225,Dongqing Road, garoms@163.com
Changzhou Jiana Chemical Co.,Ltd

website:http://www.jianachem.com

Contact:86-0519-88731808

Address:Zhenglu Town Wujin City, Jiangsu Province
Shandong Jiulong Hisince Pharmaceutical Co.,Ltd.

Contact:+86-15853188990

Address:Huadian Pioneer Park, Huadian Township, Qihe County, Dezhou City, Shandong, P.R.China
wuxi huabin bio-tech Co.,Ltd(expird)

Contact:86-0510-85133006

Address:hubin road NO157

Relevant to this article

New Molybdenocene Dihydrocarbyls

Doi:10.1016/S0022-328X(00)99758-4
(1987)
2-Aminoethanesulfonic acid: An efficient organocatalyst for green synthesis of spirooxindole dihydroquinazolinones and novel 1,2-(dihydroquinazolin-3(4H)isonicotinamides in water

Doi:10.1080/00397911.2019.1692868
(2020)
Facile access of well-defined stable divalent lead compounds with small organic substituents

Doi:10.1021/om801167c
(2009)
HIGH- AND ATMOSPHERIC-PRESSURE CYCLOADDITION OF TRICHLOROACETYL ISOCYANATE TO 3,4-DI-O-ACETYL-L-RHAMNAL

Doi:10.1016/S0040-4020(01)86897-6
(1987)
1-Methyl-4-phenyl-1,2,3,6-tetrahydropyridine Analogues. Inactivation of Monoamine Oxidase by Conformationally Rigid Analogues of N,N-Dimethylcinnamylamine

Doi:10.1021/jm00403a013
(1988)
Hansch analysis of veratric acid derivatives as antimicrobial agents

Doi:10.1016/j.ejmech.2008.05.008
(2009)

Article Doi