An Easy Route to Dibenzazepines via Nitrile Ylide Cyclisation: the Electrocyclic Equivalent of a Bischler-Napieralski Reaction

DOI: 10.1039/c39870001367

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1367 - 1368 (1987)

Update date:2022-07-30

Topics:

Authors:

Groundwater, Paul W.

Strutherts-Semple, Claire

Sharp, John T.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39870001367

N-(2-Arylbenzyl)benzimidoyl chlorides (9) are converted into dibenzazepines (6) by treatment with potassium t-butoxide, via cyclisation of nitrile ylides (4).

Full text of DOI:10.1039/c39870001367

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:C₂₂H₁₈ClNO₂

Cas No:114049-95-5

R&D Labs maybe for 114049-95-5

Beijing Tianjia Chemical Science & Technology Co.,Ltd

Contact:86-0550-2392698

Address:No.388, Shiliang Road (East),
Jingzhou TianHe Sci&Tech Chemical Co., Ltd.

Contact:86-716-8331612

Address:Jiangjin Road, #18, High-grade technology industries development district, Jingzhou city, Hubei province
Exploiter Molybdenum Co.,Ltd

Contact:86-379-63338609

Address:Jiudian Village,Deting Town,Song County,Luoyang
Feis International Trade Co,. Ltd

Contact:13961823444-18235944442

Address:Wuxi jiangsu
Zhejiang kehong chemical co., ltd

Contact:0086-575-85522000

Address:xiner center RD binhai industrial zone shaoxing zhejiang province P.R.China,312073

Relevant to this article

STUDIES ON A BIOMIMETIC APPROACH TO AEROTHIONIN AND PSAMMAPLYSIN-A

Doi:10.1016/S0040-4039(00)96672-3
(1987)
Synthesis of 3,4-Disubstituted 3,4-Dihydro-2-pyrones via 2-(Silyloxy)pyrylium Salts: Regioselective Introduction of Substituents into 2-Pyrones

Doi:10.1021/jo00269a034
(1989)
Synthesis and thromboxane A2 antagonist activity of N-benzyltrimetoquinol analogues.

Doi:10.1021/jm00403a006
(1988)
Doi:10.1139/v57-035
(1957)
P2-achiral, P'-extended alpha-ketoamide inhibitors of calpain I.

Doi:10.1016/S0960-894X(99)00392-3
(1999)
Enantioselective Synthesis and Conformational Study of Cyclohexene Carbocyclic Nucleosides

Doi:10.1021/jo9908288
(1999)

Article Doi