An Easy Route to Dibenzazepines via Nitrile Ylide Cyclisation: the Electrocyclic Equivalent of a Bischler-Napieralski Reaction

DOI: 10.1039/c39870001367

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1367 - 1368 (1987)

Update date:2022-07-30

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Authors:

Groundwater, Paul W.

Strutherts-Semple, Claire

Sharp, John T.

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Article abstract of DOI:10.1039/c39870001367

N-(2-Arylbenzyl)benzimidoyl chlorides (9) are converted into dibenzazepines (6) by treatment with potassium t-butoxide, via cyclisation of nitrile ylides (4).

Full text of DOI:10.1039/c39870001367

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