Journal of Organic Chemistry p. 2602 - 2608 (1988)
Update date:2022-09-26
Topics:
Gillard, John W.
Fortin, Rejean
Morton, Howard E.
Yoakim, Christiane
Quesnelle, Claude A.
at al.
The preparation and evaluation of a new class of alcohol-protecting groups, the alkoxydiphenylsilyl ethers, are described.In particular, tert-butoxydiphenylsilyl ethers, which can be formed from primary, secondary, or tertiary alcohols and tert-butoxydiphenylsilyl chloride, offer the useful synthetic properties of acid stability and high fluoride reactivity.Opportunities for selective silyl group cleavage are highlighted.
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