Intra- and Intermolecular Diels-Alder Reactions of Glutaconaldehyde Derivatives

DOI: 10.1021/jo00244a005

Source and publish data:

Journal of Organic Chemistry p. 1862 - 1871 (1988)

Update date:2022-08-04

Topics: NMR spectroscopy Catalyst Solvent Conjugated diene Dienophile Reaction Vessel Cyclic Product

Authors:

Becher, Jan

Nielsen, Helle Chris

Jacobsen, Jens Peter

Simonsen, Ole

Clausen, Helen

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Article abstract of DOI:10.1021/jo00244a005

The intramolecular Diels-Alder reaction of the alcohols 10a-d and maleic anhydride gave the cis-fused cycloadducts 12a-d, whereas the esters 13a and 13c prepared from 10a and fumaric acid ethyl or methyl ester monochloride produced trans-fused adducts 14a

Full text of DOI:10.1021/jo00244a005

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