CHIRAL FOUR-MEMBERED CYCLIC NITRONES; ASYMETRIC INDUCTION IN THE (4+2)-CYCLOADDITION REACTION OF CHIRAL YNAMINES AND NITROALKENES

DOI: 10.1016/S0040-4039(01)91385-1

Source and publish data:

Tetrahedron Letters p. 6397 - 6400 (1987)

Update date:2022-07-30

Topics:

Authors:

Elburg, P. A. van

Honing, G. W. N.

Reinhoudt, D. N.

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Article abstract of DOI:10.1016/S0040-4039(01)91385-1

Chiral four-membered cyclic nitrones were synthesized by the asymmetric (4+2)-cycloaddition of nitroalkenes 1 and chiral ynamines 2.The subsequent stereoselective addition of nucleophiles to these nitrones enabled the synthesis of chiral N-hydroxyazetidines.

Full text of DOI:10.1016/S0040-4039(01)91385-1

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