Subtle Effects in the Asymmetric Epoxidation: Dependence of Kinetic Resolution Efficiency on the Monodentate Alkoxide Ligands of the Bystander Titanium Center

DOI: 10.1021/jo00025a003

Source and publish data:

Journal of Organic Chemistry p. 6966 - 6968 (1991)

Update date:2022-08-05

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Authors:

McKee, Blaine H.

Kalantar, Thomas H.

Sharpless, K. Barry

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Article abstract of DOI:10.1021/jo00025a003

Complexes of diisopropyl tartrate and Ti(O^tBu)4 were found to catalyze the kinetic resolution of racemic, secondary allylic alcohols with surprisingly low efficiency relative to those generated from Ti(OⁱPr)4.This effect is documente

Full text of DOI:10.1021/jo00025a003

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