New Type of 1,3-Molecular Rearrangement of Substituted-Vinyl Alkoxymethyl Ethers and Its Application to Synthesis of 1(or 3)-Substituted 4-Alkoxybutan-2-ones

DOI: 10.1021/jo00247a015

Source and publish data:

Journal of Organic Chemistry p. 2737 - 2740 (1988)

Update date:2022-07-29

Topics: Synthesis

Authors:

Gu, Xue-Ping

Ikeda, Isao

Okahara, Mitsuo

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Article abstract of DOI:10.1021/jo00247a015

A new type of molecular rearrangement of substituted-vinyl alkoxymethyl ethers is disclosed.A 1,3-cationotropic rearrangement mechanism via relatively stable alkoxymethyl cations is postulated.The intermediacy of transient alkoxymethyl cation ion pairs is

Full text of DOI:10.1021/jo00247a015

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