New Type of 1,3-Molecular Rearrangement of Substituted-Vinyl Alkoxymethyl Ethers and Its Application to Synthesis of 1(or 3)-Substituted 4-Alkoxybutan-2-ones

DOI: 10.1021/jo00247a015

Source and publish data:

Journal of Organic Chemistry p. 2737 - 2740 (1988)

Update date:2022-07-29

Topics: Synthesis

Authors:

Gu, Xue-Ping

Ikeda, Isao

Okahara, Mitsuo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00247a015

A new type of molecular rearrangement of substituted-vinyl alkoxymethyl ethers is disclosed.A 1,3-cationotropic rearrangement mechanism via relatively stable alkoxymethyl cations is postulated.The intermediacy of transient alkoxymethyl cation ion pairs is

Full text of DOI:10.1021/jo00247a015

Products guided by the article

Product name:1-(N-benzyl-N-methylamino)-4-methoxybutan-2-one

Cas No:114250-58-7

R&D Labs maybe for 114250-58-7

Jiangsu Fengshan Group Co., Ltd.

Contact:86-25-86558671

Address:1903,Central International Mansion 105-6 North Zhongshan Road, Nanjing, China
ZHANGJIAGANG FREE TRADE ZONE YONG HAN INTERNATIONAL TRADING CO., LTD(expird)

Contact:86 512 57910558

Address:qianjin M road
Ningbo Inno Pharmchem Co., Ltd.

Contact:86-574-87319282

Address:6F-5,NO.163 RUIQING RD.,NINGBO 315000 CHINA
SHANDONG CREDAGRI CHEMICAL CO., LTD.

Contact:+86-531-88872050

Address:ROOM 601A, BUILDING 2, SHUNTAI SQUARE, NO. 2000 SHUNHUA ROAD, HI-TECH DEVELOPMENT ZONE, JINAN, CHINA.
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China

Relevant to this article

Friedel-crafts cyclialkylations of some epoxides. 2. Stereospecificity, substituent, product, and kinetic studies

Doi:10.1021/jo00379a021
(1987)
Metal-free dihydrogen activation chemistry: Structural and dynamic features of intramolecular P/B pairs

Doi:10.1039/b815832k
(2009)
Role of Ring Ortho Substituents on the Configuration of Carotenoid Polyene Chains

Doi:10.1021/acs.orglett.7b03930
(2018)
Pyridine-facilitated phenylselenoetherification of some tertiary alkenols

Doi:10.1002/hc.1072
(2001)
Doi:10.1021/ja01191a532
(1948)
WO₃-30% H₂O₂-cinchona alkaloids: A new heterogeneous catalytic system for the asymmetric oxidation of sulfides and the kinetic resolution of racemic sulfoxides

Doi:10.1016/S0957-4166(02)00865-0
(2003)

Article Doi