Tetrahedron p. 1007 - 1016 (1989)
Update date:2022-08-03
Topics:
Hull, Caroline
Mortlock, Simon V.
Thomas, Eric J.
α-Methylbut-2-enylstannanes (7) - (9) react stereoselectively on heating with aldehydes to form anti-5-hydroxy-4-methyl-Z-pent-2-enes (16) and (17).In the presence of BF3*Et2O, the major products are the corresponding syn-5-hydroxy-4-methyl-E-pent-2-enes
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Doi:10.1021/jo00243a054
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