UEBERGANGSMETALL-HETEROALLEN-KOMPLEXE XVII. REAKTIONEN DES AZA-ALLYL-KOMPLEXES (KETENIMIN)Fe2(CO)6 MIT PHOSPHANEN

DOI: 10.1016/0022-328X(87)80230-9

Source and publish data:

Journal of Organometallic Chemistry p. 85 - 100 (1987)

Update date:2022-08-04

Topics:

Authors:

Sielisch, Thomas

Behrens, Ulrich

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0022-328X(87)80230-9

The aza-allyl complex (ketene imine)Fe2(CO)6 (3a) reacts with phosphanes PR3 to give substitution products of the type (ketene imine)Fe2(CO)5PR3 (4a,b).In addition, the phosphane PMe3 yields a ferrole complex (5).Phosphites react with complex 3a to form mono- and di-substitution products (ketene imine)Fe2(CO)5P(OR)3 (4c, d) and (ketene imine)Fe2(CO)4(P(OR)3)2 (6).Diphosphanes yield substituted complexes of type (ketene imine)Fe2(CO)4(μ-Ph2P-PPh2) (7).The structures of (ketene imine)Fe2(CO)5PMe3 (4a), the ferrole complex 5, and (ketene imine)Fe2(CO)4(μ-Ph2PCH2CH2PPh2) (7b) were determined by X-ray analysis.

Full text of DOI:10.1016/0022-328X(87)80230-9

Products guided by the article

Product name:(CH₃)3P(CO)2FeFe(CO)3((C₆H₅)2CCN(C₆H₅))

Cas No:114741-87-6

R&D Labs maybe for 114741-87-6

NIGNXIA XINDACHANG TECHNOLOGY CO.,LTD

Contact:86-0951-7815345

Address:North side of Qiyuan Road, west side of Yuanfeng Highway, New Material Park, Ningdong Energy and Chemical Industry Base, Ningxia,China
ZK Biochem Group Co., Ltd

Contact:+86-532-80762375

Address:No. 6, Hongkong Middle Road, Qingdao, China
LIANYUNGANG YC FINE CHEMICAL CO., LTD

Contact:+86-518-858 99188

Address:Shangdong Modern Bldg, South Greenpark Road, Lianyungang, Jiangsu Pro. China
Chongqing Rong＆Quan Pharmaceutical Technology Co. , Ltd.

Contact:86-023-65268721

Address:No. 7, Manshanhong Village, Pingdingshan, Shapingba District, Chongqing Province, China
BAILINWEI TECHNOLOGY CO.,LTD

Contact:86-170-000000

Address:No.168 Road,han city, China

Relevant to this article

Functionalized 3-benzylidene-indolin-2-ones: Inducers of NAD(P)H-quinone oxidoreductase 1 (NQO1) with antiproliferative activity

Doi:10.1016/j.bmc.2008.12.052
(2009)
Design, synthesis, and biological evaluation of novel 1-(1H-1,2,4-triazole-1-yl)-2-(2,4-difluorophenyl)-3-substituted benzylamino-2-propanols

Doi:10.1016/j.bmcl.2009.01.048
(2009)
PREPARATIOM OF NOVEL PYRANOSYL FLUORIDES OF 3-DEOXY-D-manno-2-OCTULOSONIC ACID (KDO) FEASIBLE FOR SYNTHESIS OF KDO α-GLYCOSIDES

Doi:10.1016/S0040-4039(01)91351-6
(1987)
Studies on cardiac ingredients of plants. V. Chemical transformation of proscillaridin and biological activities of derivatives

Doi:10.1248/cpb.36.48
(1988)
Multiple Aryne Insertions into Oxindoles: Synthesis of Bioactive 3,3-Diarylated Oxindoles and Dibenzo[b,e]azepin-6-ones

Doi:10.1021/acs.orglett.6b03224
(2016)
Resonance Raman Spectra of Dioxygen Adducts of Cobalt Porphyrins. Spectroscopic Manifestation of Vibrationally Coupled Dioxygen and Energy Matching of Interactive Modes

Doi:10.1021/ja00222a009
(1988)

Article Doi