1-Oxaspironona-3,6,8-trien-2-one: Neuartige Produkte aus Acetylenen und Kohlenmonoxid in Gegenwart von Kobaltcarbonyl

DOI: 10.1016/0022-328X(89)88056-8

Source and publish data:

Journal of Organometallic Chemistry p. 223 - 230 (1989)

Update date:2022-09-26

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Authors:

Dehmlow, Eckehard V.

Winterfeldt, Andreas

Pickardt, Joachim

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Article abstract of DOI:10.1016/0022-328X(89)88056-8

Reaction of the bulky aliphatic terminal acetylenes adamantyl(1)-acetylene (1a) and t-butyl-acetylene (1b) with CO, catalyzed by Co2(CO)8, gives the 3:2 adducts 3,6,9-trisadamantyl- or 3,6,9-tri-t-butyl-1-oxaspiro<4.4>nona-3,6,8-trien-2-one (4a or 4b, res

Full text of DOI:10.1016/0022-328X(89)88056-8

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