Perfluoralkyl-thwarted Rearrangement of Quinol Esters. Formation of Catechol Derivatives via 1,3-Migration of Acyloxyl Group

DOI: 10.1246/cl.1988.127

Source and publish data:

Chemistry Letters p. 127 - 130 (1988)

Update date:2022-08-03

Topics:

Authors:

Suzuki, Hitomi

Shiraishi, Yasukazu

Shimokawa, Kazuhiro

Uno, Hidemitsu

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Article abstract of DOI:10.1246/cl.1988.127

Treatment of 4-perfluoroalkyl-4-quinols with acetic anhydride-sulfuric acid was found to lead to 1,2- and 1,3-migration of acetoxyl group in initially formed quinol acetates followed by aromatization to give a mixture of 4-perfluoroalkylresorcinol diaceta

Full text of DOI:10.1246/cl.1988.127

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