Sterically Hindered Chalcogenolato Complexes. Mono- and Di-meric Thiolates and Selenolates of Zinc and Cadmium; Structure of t3-2,4,6)2>2>, the First Three-co-ordinate Cadmium-Selenium Complex

DOI: 10.1039/DT9910002317

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 2317 - 2323 (1991)

Update date:2022-07-29

Topics:

Authors:

Bochmann, Manfred

Webb, Kevin J.

Hursthouse, Michael B.

Mazid, Muhammed

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Article abstract of DOI:10.1039/DT9910002317

Protolysis of M2 (M = Zn or Cd) with arenechalcogenols 2,4,6-R3C6H2EH (E = S or Se; R = Me, Prⁱ or Bu^t) gives the corresponding chalcogenolato complexes M(EC6H2R3-2,4,6)2 in high yield.Complexes with R = Me form co-ordinat

Full text of DOI:10.1039/DT9910002317

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