Organometallics p. 1882 - 1883 (1988)
Update date:2022-07-29
Topics:
Ando, Wataru
Tsumuraya, Takeshi
1,1,2,2-Tetrakis(2,6-diethylphenyl)digermirane (3) was prepared by the reaction of tetrakis(2,6-diethylphenyl)digermene (2) with diazomethane. The photolysis of 3 with a high-pressure mercury lamp yields germene 4 and germylene 5. The digermirane 3 reacts with pyridine N-oxide, sulfur, and selenium to yield the insertion products of O, S, and Se into the germanium-germanium bond. 2,2,3,3-Tetrakis(2,6-diethylphenyl)azadigermiridine (12) was prepared by the reaction of 2 with phenyl azide.
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Doi:10.1021/om5013117
(2015)Doi:10.1055/s-0028-1087814
(2009)Doi:10.1021/acs.orglett.0c01717
(2020)Doi:10.1016/j.ejmech.2008.10.015
(2009)Doi:10.1021/ja00225a037
(1988)Doi:10.1016/S0040-4039(00)96533-X
(1987)
