STEREOCHEMICAL STUDIES, 105. SATURATED HETEROCYCLES, 109 SYNTHESIS AND STERIC STRUCTURES OF PERHYDRO-4,1-BENZOXAZEPIN-2-ONES

DOI: 10.1016/S0040-4020(01)90311-4

Source and publish data:

Tetrahedron p. 4359 - 4366 (1987)

Update date:2022-09-26

Topics:

Authors:

Bernath, Gabor

Fueloep, Ferenc

Sohar, Pal

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Article abstract of DOI:10.1016/S0040-4020(01)90311-4

-cis- and trans-2-Hydroxymethylcyclohexanol were cyclized with ethyl chloroacetate or ethyl 2-chloropropionate in the presence of sodium hydride to synthesize stereoisomeric perhydro-4,1-benzoxazepin-2-ones (4-9).The relative configurations and predominant conformation of the compounds prepared were confirmed by ¹H and ¹³C NMR spectroscopy.

Full text of DOI:10.1016/S0040-4020(01)90311-4

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