Journal of Organic Chemistry p. 1562 - 1570 (1989)
Update date:2022-09-26
Topics:
Salomon, Robert G.
Mazza, Samuel M.
Lal, Kasturi
A total synthesis from (+)-nopinone establishes as 10f and 11f respectively the structures, including absolute stereochemistry, for robustadials A, and B, natural products isolated from the antimalarial Chinese herbal medicinal extract of Eucalyptus robusta leaves.The 1H and 13C NMR spectral assignments for robustadial B dimethyl ether (11e) are examined in detail.It is then shown that the Overhauser enhancement data interpreted originally to support 1b as the structure for this ether actually consistent with both structures 1b and 11e.
View Morejiangsu haian chemical co.,ltd.
Contact:86-513-15851283853
Address:No.99,Changjiang West Road,Haian County,Jiangsu Province,China
Laohekou Jinghong Chemical Co.,Ltd
Contact:+86-0710-3702747
Address:163.East,Huagong Road,Laohekou
Shenzhen Sunrising Industry Co., ltd.
Contact:+86 755 86571158 / 86571159 / 86571160
Address:2108 ZHENYE INT. BUSINESS CENTER,NO.3101-90 QIANHAI RD, NANSHAN,SHENZHEN, CHINA
Contact:+49-9398-993127
Address:Untertorstr. 27
Shanghai KFSL Pharmaceutical Technology Co.,Ltd.
Contact:+86-21-39971718
Address:859 jiadingchengliu shanghai
Doi:10.1021/acs.orglett.5b01737
(2015)Doi:10.1021/ic202435r
(2012)Doi:10.1039/c5cc05740j
(2015)Doi:10.1016/j.ejmech.2008.06.027
(2009)Doi:10.1016/j.ejmech.2014.04.046
(2014)Doi:10.1021/acs.jmedchem.6b00674
(2016)