Birch Reduction of Arylphosphines

DOI: 10.1039/C39870001700

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1700 - 1701 (1987)

Update date:2022-07-29

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Authors:

Doorn, Johannes A. van

Meijboom, Nico

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Article abstract of DOI:10.1039/C39870001700

In contrast to unsubstituted tri(aryl)phosphines, bis(p-dimethylaminophenyl)phenylphosphine is not cleaved by sodium in liquid ammonia; instead, the hitherto unknown Birch product is formed via an intermediary phosphinocyclohexadienyl anion.

Full text of DOI:10.1039/C39870001700

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