Journal of the Chemical Society. Chemical communications p. 1700 - 1701 (1987)
Update date:2022-07-29
Topics:
Doorn, Johannes A. van
Meijboom, Nico
In contrast to unsubstituted tri(aryl)phosphines, bis(p-dimethylaminophenyl)phenylphosphine is not cleaved by sodium in liquid ammonia; instead, the hitherto unknown Birch product is formed via an intermediary phosphinocyclohexadienyl anion.
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Doi:10.1021/acs.orglett.0c01717
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