LIQUID-LIQUID AND SOLID-LIQUID PHASE-TRANSFER GLYCOSYLATION OF PYRROLOPYRIMIDINES : STEREOSPECIFIC SYNTHESIS OF 2-DEOXY-β-D-RIBOFURANOSIDES RELATED TO 2'-DEOXY-7-CARBAGUANOSINE

DOI: 10.1039/P19880000697

Source and publish data:

Journal of the Chemical Society. Perkin transactions I p. 697 - 702 (1988)

Update date:2022-09-26

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Authors:

Seela, Frank

Westermann, Bernhard

Bindig, Uwe

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Article abstract of DOI:10.1039/P19880000697

The yield of phase-transfer glycosylation of 2-amino-4-methoxy-7H-pyrrolo<2,3-d>pyrimidine (3b) with 2-deoxy-3,5-di-O-(p-toluoyl)-α-D-erythro-pentofuranosyl chloride (4) is limited under liquid-liquid conditions (50percent aq.NaOH, CH2Cl2, Bu4NHSO4) due t

Full text of DOI:10.1039/P19880000697

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