Intramolecular Hydrogen Abstraction in Ketone Photochemistry: the First Examples of ζ-Hydrogen Abstraction

DOI: 10.1039/c39870001673

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Journal of the Chemical Society. Chemical communications p. 1673 - 1674 (1987)

Update date:2022-09-26

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Authors:

Carless, Howard A. J.

Mwesigye-Kibende, Samson

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Article abstract of DOI:10.1039/c39870001673

U.v. irradiation of the aryl ketones (1), (6), and (9) leads to intramolecular hydrogen abstraction via a nine-membered transition state, yielding tetrahydrobenzoxepinols.

Full text of DOI:10.1039/c39870001673

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