LIMITATIONS IN THE APPLICATION OF ANIONIC OXY-COPE SIGMATROPY TO ELABORATION OF THE FORSKOLIN NUCLEUS

DOI: 10.1016/0040-4020(89)80038-9

Source and publish data:

Tetrahedron p. 107 - 124 (1989)

Update date:2022-07-29

Topics: Stereochemistry Reaction Conditions Scalability Reactivity and Selectivity Side Reactions

Authors:

Paquette, Leo A.

Oplinger, Jeffrey A.

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Article abstract of DOI:10.1016/0040-4020(89)80038-9

The functionalized bicyclo<2.2.2>octenone 6 has been synthesized in four steps from 2,4,4-trimethyl-2-cyclohexenone.This ketone undergoes 1,2-addition with 6-lithiodihydropyran to deliver alcohols 16 and 17 in a 1:1.8 ratio.The potassium salt of 17 experi

Full text of DOI:10.1016/0040-4020(89)80038-9

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