Tetrahedron p. 107 - 124 (1989)
Update date:2022-07-29
Topics: Stereochemistry Reaction Conditions Scalability Reactivity and Selectivity Side Reactions
Paquette, Leo A.
Oplinger, Jeffrey A.
The functionalized bicyclo<2.2.2>octenone 6 has been synthesized in four steps from 2,4,4-trimethyl-2-cyclohexenone.This ketone undergoes 1,2-addition with 6-lithiodihydropyran to deliver alcohols 16 and 17 in a 1:1.8 ratio.The potassium salt of 17 experi
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(2009)Doi:10.1016/j.tet.2020.131346
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(1988)
